商业化
锰
溶解
水溶液
材料科学
氧化还原
储能
氧化锰
插层(化学)
纳米技术
化学工程
化学
无机化学
冶金
业务
有机化学
工程类
营销
功率(物理)
物理
量子力学
作者
Jiafeng Lei,Liwei Jiang,Yi‐Chun Lu
出处
期刊:Chemical physics reviews
[American Institute of Physics]
日期:2023-05-22
卷期号:4 (2)
被引量:9
摘要
Aqueous manganese (Mn)-based batteries are promising candidates for grid-scale energy storage due to their low-cost, high reversibility, and intrinsic safety. However, their further development is impeded by controversial reaction mechanisms and low energy density with unsatisfactory cycling stability. Here, we summarized various types of emerging aqueous Mn-based batteries based on the active redox couples, including liquid–solid deposition/dissolution reactions of Mn0/Mn2+ and Mn2+/MnO2, liquid–liquid conversion reactions of Mn2+/Mn3+ and MnO42−/MnO4−, and solid–solid intercalation reaction of XMnOy/MnOy (X: cations) with manganese oxide as the host materials. A critical review of the fundamental understanding of their physicochemical properties in each reaction, scientific challenges, and improvement strategies is presented. Finally, perspectives on aqueous Mn-based batteries design for future commercialization are highlighted.
科研通智能强力驱动
Strongly Powered by AbleSci AI