化学
单层
电子能量损失谱
高分辨电子能量损失谱
乙烯
金属
氢
碳氢化合物
氢-氘交换
光化学
光谱学
吸附
Crystal(编程语言)
结晶学
分析化学(期刊)
电子
催化作用
物理化学
有机化学
程序设计语言
物理
量子力学
生物化学
计算机科学
作者
Bruce E. Koel,Brian E. Bent,Gábor A. Somorjai
出处
期刊:Surface Science
[Elsevier]
日期:1984-10-01
卷期号:146 (1): 211-228
被引量:118
标识
DOI:10.1016/0039-6028(84)90238-3
摘要
We have combined high resolution electron energy loss spectroscopy (HREELS) with a high-pressure/low-pressure (HPLP) system to study the behavior of the monolayer structure of stable hydrocarbon species that form on single-crystal metal surfaces during catalytic reactions at atmospheric pressure. We find that a monolayer of adsorbed ethylidyne (CCH3) on Rh(111) at 310 K does not hydrogenate to ethylene or ethane in one atmosphere of static D2. The methyl group hydrogens exchange with deuterium is a slow process. The amount of exchange depends strongly on the amount of uncovered, bare-metal surface, but little on the hydrogen pressure. A mechanism for H, D exchange involving ethylidene (CHCH3) as an intermediate is proposed.
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