Ultrastretchable E‐Skin Based on Conductive Hydrogel Microfibers for Wearable Sensors

Abstract Conductive microfibers play a significant role in the flexibility, stretchability, and conductivity of electronic skin (e‐skin). Currently, the fabrication of conductive microfibers suffers from either time‐consuming and complex operations or is limited in complex fabrication environments. Thus, it presents a one‐step method to prepare conductive hydrogel microfibers based on microfluidics for the construction of ultrastretchable e‐skin. The microfibers are achieved with conductive MXene cores and hydrogel shells, which are solidified with the covalent cross‐linking between sodium alginate and calcium chloride, and mechanically enhanced by the complexation reaction of poly(vinyl alcohol) and sodium hydroxide. The microfiber conductivities are tailorable by adjusting the flow rate and concentration of core and shell fluids, which is essential to more practical applications in complex scenarios. More importantly, patterned e‐skin based on conductive hydrogel microfibers can be constructed by combining microfluidics with 3D printing technology. Because of the great advantages in mechanical and electrical performance of the microfibers, the achieved e‐skin shows impressive stretching and sensitivity, which also demonstrate attractive application values in motion monitoring and gesture recognition. These characteristics indicate that the ultrastretchable e‐skin based on conductive hydrogel microfibers has great potential for applications in health monitoring, wearable devices, and smart medicine.