碳化
超级电容器
电解质
材料科学
多孔性
杂原子
碳纤维
燃烧
化学工程
比表面积
复合材料
有机化学
电容
化学
电极
催化作用
工程类
复合数
扫描电子显微镜
物理化学
戒指(化学)
作者
Bolang Chen,Dongling Wu,Tao Wang,Fang Yuan,Dianzeng Jia
标识
DOI:10.1016/j.cej.2023.142163
摘要
Herein, the feasibility of simple and quick to fabricate porous biocarbon materials by a universal flame burning carbonization synthetic strategy is investigated. Cotton, dandelion and catkin are fluffy that contain lots of air between the tissues, which are low ignition point and flammable substances, they are easily lighted and carbonized. K2CO3-KCl not only play the role of activator and template agent, but also cover the surface of substance in the form of molten state to isolate air with biocarbon and prevent the burn out of biomass. The prepared carbon has hierarchical porous structure, large specific surface area and abundant heteroatoms doping, and can reach a high specific capacitance of 367 F g−1 in 6 M KOH. In addition, we also prepare a large voltage window of K2CO3-glycol-arginine electrolyte, and the assembled symmetric supercapacitor with the prepared electrolyte and porous carbon exhibits an energy density of 30.7 Wh kg−1 and a wide operating temperature from −25 to 100 °C. The practicable of flame burning rapid carbonization strategy, recycling K salt and large-scale production are verified. This study uncovers a new possibility for the rapid and commercial production of biomass based porous carbon materials for high performance supercapacitor.
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