Defect‐Induced Dense Amorphous/Crystalline Heterophase Enables High‐Rate and Ultrastable Sodium Storage

Currently, the construction of amorphous/crystalline (A/C) heterophase has become an advanced strategy to modulate electronic and/or ionic behaviors and promote structural stability due to their concerted advantages. However, their different kinetics limit the synergistic effect. Further, their interaction functions and underlying mechanisms remain unclear. Here, a unique engineered defect-rich V