催化作用
镍
范围(计算机科学)
化学
组合化学
终端(电信)
钯
反应条件
氯化物
有机化学
计算机科学
电信
程序设计语言
作者
Stéphanie Ortial,Henry C. Fisher,Jean‐Luc Montchamp
摘要
The room-temperature hydrophosphinylation of unactivated monosubstituted alkenes using phosphinates (ROP(O)H2) and catalytic NiCl2 in the presence of dppe is described. The method is competitive with prior palladium-catalyzed reactions and uses a much cheaper catalyst and simple conditions. The scope of the reaction is quite broad in terms of unactivated terminal olefins, proceeds at room temperature, often avoids chromatographic purification, and allows one-pot conversion to various organophosphorus compounds.
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