Tuning the Unloading and Infiltrating Behaviors of Li‐Ion by a Multiphases Gradient Interphase for High‐Rate Lithium Metal Anodes

The random distribution of organic-phases (OPs) and inorganic-phases (IOPs) in native solid electrolyte interface (SEI) derived a sluggish Li-ion de-solvation and transmission, impairing the high-rate performance of lithium metal anodes (LMAs). Herein, a multiphases gradient distribution hybrid interface is constructed on metallic Li by surface chemical reconstruction. Theoretical simulations and experiments verify that the Li-ion unloading and infiltrating behaviors are tuned by functional complementary effects, enabling speedy kinetics. The upper OPs with polar functional group (─COO