溶剂化
锂(药物)
材料科学
硫黄
离子
化学
有机化学
心理学
精神科
作者
Guorui Cai,Hongpeng Gao,Mingqian Li,Varun Gupta,John Holoubek,Tod A. Pascal,Ping Liu,Zheng Chen
标识
DOI:10.1002/anie.202316786
摘要
Abstract Achieving increased energy density under extreme operating conditions remains a major challenge in rechargeable batteries. Herein, we demonstrate an all‐fluorinated ester‐based electrolyte comprising partially fluorinated carboxylate and carbonate esters. This electrolyte exhibits temperature‐resilient physicochemical properties and moderate ion‐paired solvation, leading to a half solvent‐separated and half contact‐ion pair in a sole electrolyte. As a result, facile desolvation and preferential reduction of anions/fluorinated co‐solvents for LiF‐dominated interphases are achieved without compromising ionic conductivity (>1 mS cm −1 even at −40 °C). These advantageous features were found to apply to both lithium metal and sulfur‐based electrodes even under extreme operating conditions, allowing stable cycling of Li || sulfurized polyacrylonitrile (SPAN) full cells with high SPAN loading (>3.5 mAh cm −2 ) and thin Li anode (50 μm) at −40, 23 and 50 °C. This work offers a promising path for designing temperature‐resilient electrolytes to support high energy density Li metal batteries operating in extreme conditions.
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