单宁酸
水溶液
粘度
丙烯酰胺
丙烯酸
化学
化学工程
高分子化学
材料科学
核化学
有机化学
聚合物
复合材料
工程类
单体
共聚物
作者
Ramses S. Meleán Brito,Juan M. Milanesio,M. Belén Oviedo,Juan M. Padró,Miriam C. Strumia,Facundo Mattea
出处
期刊:ACS applied polymer materials
[American Chemical Society]
日期:2024-04-06
卷期号:6 (8): 4462-4474
被引量:1
标识
DOI:10.1021/acsapm.3c03056
摘要
This study focuses on the synthesis of a polymer through the grafting of tannic acid onto poly(acrylamide-co-acrylic acid). The main goal is to generate polymers with lateral branched structures with the versatile bonding abilities associated with tannic acid and then study their ability to modify the viscosity of aqueous solutions for potential application in enhanced oil recovery. The synthesized macromolecules were characterized using Fourier transform infrared spectroscopy, 1H-nuclear magnetic resonance spectroscopy, ultraviolet–visible spectroscopy, size exclusion chromatography coupled with multi-angle light scattering and differential refractive index detection, as well as fluorescence spectroscopy. These techniques were employed to confirm and quantify the incorporation of tannic acid. The results showed that adding 0.4, 4.0, and 10.0% w/w tannic acid in the reaction mixture produced polymers with incorporations of the branched monomer ranging from 0.06 to 6.92% w/w. The rheological properties of aqueous solutions of the obtained polymers indicated changes in the intra- and intermolecular interactions that were also interpreted by density functional theory simulations. Results showed that the viscosity of the solutions was at least 4.4 times higher than that of the original poly(acrylamide-co-acrylic acid) in water.
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