Dynamic Zn/Electrolyte Interphase and Enhanced Cation Transfer of Sol Electrolyte for All‐Climate Aqueous Zinc Metal Batteries

Zn metal as one of the promising anodes of aqueous batteries possesses the notable advantages, but it faces severe challenges from serious side reactions and notorious dendrite growth. Herein, ultrathin nanosheets of α-zirconium phosphate (ZrP) are explored as an electrolyte additive. The nanosheets not only create a dynamic and reversible interphase on Zn, but also promote the Zn2+ transportation in the electrolyte, especially in the outer Helmholtz plane near ZrP. Benefited from the enhanced kinetics and dynamic interphase, the pouch cells of Zn||LiMn2O4 using this electrolyte show the remarkably improved electrochemical performance under harsh conditions, i.e. Zn powders as the Zn anode, limited N/P ratio, high mass loading, and wide temperatures. The results expand the materials available for this dynamic interphase, provide the insightful understanding about the enhanced charge transfer in the electrolyte, and realize the combination of dynamic interphase and enhanced kinetics for all-climate performance.