Nonpolar Solvent Modulated Inkjet Printing of Nanoparticle Self‐Assembly Morphologies

Abstract Patterning of luminescent nanomaterials is critical in the fields of display and information encryption, and inkjet printing technology have shown remarkable significance with the advantage of fast, large‐scalable and integrative. However, inkjet printing nanoparticle deposits with high‐resolution and well controlled morphology from nonpolar solvent droplets is still challenging. Herein, a facile approach of nonpolar solvent modulated inkjet printing of nanoparticles self‐assembly patterns driven by the shrinkage of the droplet and inner solutal convection is proposed. Through regulating the solvent composition and nanoparticle concentration, multicolor light‐emissive upconversion nanoparticle self‐assembly microarrays with tunable morphologies are achieved, showing the integration of designable microscale morphologies and photoluminescences for multimodal anti‐counterfeit. Furthermore, inkjet printing of nanoparticles self‐assembled continuous lines with adjustable morphologies by controlling the coalescence and drying of the ink droplets is achieved. The high resolution of inkjet printing microarrays and continuous lines’ width < 5 and 10 µm is realized, respectively. This nonpolar solvent‐modulated inkjet printing of nanoparticle deposits approach facilitates the patterning and integration of different nanomaterials, and is expected to provide a versatile platform for fabricating advanced devices applied in photonics integration, micro‐LED, and near‐field display.