Efficient and portable cellulose-based colorimetric test paper for metal ion detection

Fabrication of metal ion detection materials generally involved problems such as high cost and complicated processes of pretreatment and operation. Herein, a novel colorimetric test paper for metal ions detection was developed based on functionalized cellulose fibers. Acetoacetyl groups were introduced on cellulose fibers by a surface esterification process. The obtained cellulose acetoacetate (CAA) fibers were made into CAA paper via a paper-making process. The CAA paper possessed robust mechanical property, thermal stability selectivity and rapid response to Fe3+ and Cu2+ ions, with an obvious naked-eye color change within 5 s. The mechanism of this visual recognition for metal ions due to that the acetoacetyl groups coordination chelated with metal ion to form six-membered ring structure, further leading to the color change of the materials. It provided a facile and universal method to prepare efficient and portable cellulose-based test paper, which has great potential in metal ion detection field.