聚乙烯吡咯烷酮
复合数
超级电容器
材料科学
化学工程
电化学
多孔性
尿素
柠檬酸
微观结构
核化学
冶金
复合材料
化学
有机化学
电极
高分子化学
工程类
物理化学
作者
M. Mamizadeh,S.M. Masoudpanah,M. Sh. Bafghi,M.P. Dabir
标识
DOI:10.1016/j.est.2023.106989
摘要
In this research, CuO/Cu2O/Cu composite powders were prepared by solution combustion synthesis method by using copper nitrate as oxidant and organic fuels. The effects of fuel type, including citric acid, glycine, urea, polyvinylpyrrolidone, and lysine, on the physicochemical and electrochemical properties were analyzed by various characterization techniques. The powders synthesized using urea had the highest amount of Cu2O phase (44.9 wt%). However, the highest amount of CuO phase (97.6 wt%) was obtained by the polyvinylpyrrolidone fuel. Except for the urea fuel with an agglomerated microstructure, the other composite powders had a porous structure with large porosities. The composite powders prepared with glycine fuel containing a mixture of CuO and Cu2O phases had the highest specific capacity of 1480 and 1117 F g−1 at the current densities of 1 and 10 A g−1, respectively, which was equivalent to the capacity retention of 75.5 %. The Cu/CuO/Cu2O//activated carbon hybrid capacitor showed the comparable performance of electrochemical energy storage, including an energy density of 9.7 Wh kg−1 at a power density of 750 W kg−1.
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