Recent Progress of Vertical Graphene: Preparation, Structure Engineering, and Emerging Energy Applications

Abstract Vertical graphene (VG) nanosheets have garnered significant attention in the field of electrochemical energy applications, such as supercapacitors, electro‐catalysis, and metal‐ion batteries. The distinctive structures of VG, including vertically oriented morphology, exposed, and extended edges, and separated few‐layer graphene nanosheets, have endowed VG with superior electrode reaction kinetics and mass/electron transportation compared to other graphene‐based nanostructures. Therefore, gaining insight into the structure‐activity relationship of VG and VG‐based materials is crucial for enhancing device performance and expanding their applications in the energy field. In this review, the authors first summarize the fabrication methods of VG structures, including solution‐based, and vacuum‐based techniques. The study then focuses on structural modulations through plasma‐enhanced chemical vapor deposition (PECVD) to tailor defects and morphology, aiming to obtain desirable architectures. Additionally, a comprehensive overview of the applications of VG and VG‐based hybrids d in the energy field is provided, considering the arrangement and optimization of their structures. Finally, the challenges and future prospects of VG‐based energy‐related applications are discussed.