Improved mechanical properties of carbon fiber/epoxy composites via fiber surface grafting of rigid-flexible chain structure

The surface topography and interface characteristics play a significant role in determining the mechanical properties of carbon fiber reinforced polymer (CFRP) composites. These features are primarily influenced by the surface chemical structures and their interactions with the matrix resin. Here, we developed a rigid-flexible coating consisting of polyetheramine (PEA) and polydopamine (PDA) on the fiber surface to control the interface and improve the mechanical properties of CFRPs. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectrum (FT-IR) results validated the successful introduction of polymeric chains and fiber surface characteristics including rough surfaces, slim polymer layers and uniform dots were examined by scanning electron microscope (SEM) and transmission electron microscopy (TEM). Contact angle tests indicate that the functionalized coating noticeably enhances the interaction force between carbon fibers, promoting improved wettability by the matrix resin. The bending and interlaminar shear strength of CFRP prepared by functional carbon fiber are increased by 45.76 % and 47.63 %, respectively. The drop weight impact (DWI) test confirms the positive effect of improved interfacial properties on the out-of-plane impact resistance of CFRPs.