Electrochemical properties of humic acid and its novel applications: A tip of the iceberg

The widely existed humic acid (HA) with abundant redox-active groups has been considered to play an important role in biogeochemistry in sediments and soils. Recent studies reported that HA showed great performance in terms of electron transfer capacity (up to HAEDC = 94 mmol e-/mol C, HAEAC = 42 mmol e-/mol C). Since HA is widely available, inexpensive and environmentally friendly, the electrochemistry of HA has been explored to apply in many fields, such as environmental remediation, detection sensor and energy storage. Whereas, these prospective applications of HA and their electrochemical principles were lack of a comprehensive summary. In this review, the electrochemical properties and the prospective electrochemical applications of HA were summarized. Simultaneously, the existing problems like shortages of traditional electrochemical characterization of HA, and future research directions about HA electrochemistry were prospected. This review provides a deeper understanding of HA electrochemistry, and also inspires ideas for environmental remediation, detection sensor and energy storage by exploring the potential application values of HA.