Programmable Droplet Bouncing on Bionic Functional Surfaces for Continuous Electricity Generation

Abstract The natural phenomenon of droplets bouncing on various surfaces holds remarkable potential for applications like water transportation, self‐cleaning, antifreezing, etc. However, achieving precisely controlled patterned droplet bouncing on functional surfaces with accurately controlled factors like bouncing velocity and trajectory in three dimensions remains a formidable challenge. In this context, a concept of bionic hydrophobic functional surfaces composed of mushroom‐like microstructures is introduced. These microstructures are crafted using the projection microstereolithography (PµSL) based 3D printing technique, subsequently coated with a hydrophobic spray. By finely adjusting the geometric attributes and inclination angles of these micromushrooms, the ability is gained to meticulously manipulate the bouncing velocity and trajectory of water droplets. The most optimal performance is demonstrated by a droplet exhibiting a maximal jumping distance and height respectively of 2.5 and 7.1 mm with 50° inclined micromushrooms. Notably, these specially designed micromushrooms orchestrate diverse behaviors in droplet bouncing, encompassing patterned bouncing, antigravity jumps, and directional water transportation. Additionally, the functional surface's adaptable self‐cleaning capability facilitates the harnessing of energy from rainfall on large surfaces, offering potential applications in realms, such as self‐cleaning mechanisms, droplet capture, water conveyance, and clean energy generation.