Modulating electronic structure by interlayer spacing and twist on bilayer bismuthene

Abstract Modulation of the electronic structure has played a crucial role in advancing the field of two-dimensional materials, but there are still many unexplored directions, such as the twist angle for a novel degree of freedom, for modulating the properties of heterostructures. We observed a distinct pattern in the energy bands of bilayer bismuthene, demonstrating that modulating the twist angle and interlayer spacing significantly influences interlayer interactions. Our study of various interlayer spacings and twist angles revealed a close relationship between bandgap size and interlayer spacing, while the twist angle notably affects the shape of the energy bands. Furthermore, we observed a synergistic effect between these two factors. As the twist angle decreases, the energy bands become flat, and flat bands can be generated without requiring a specific angle on bilayer bismuthene. Our results suggest a promising way to tailor the energy band structure of bilayer 2D materials by varying the interlayer spacing and twist angle.