化学
电池(电)
电解质
氧化还原
有机自由基电池
阴极
离子液体
无机化学
阳极
化学工程
有机化学
电极
催化作用
物理化学
功率(物理)
工程类
物理
量子力学
作者
Huajun Tian,Shunlong Zhang,Zhen Meng,Wei He,Wei‐Qiang Han
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2017-04-24
卷期号:2 (5): 1170-1176
被引量:134
标识
DOI:10.1021/acsenergylett.7b00160
摘要
Rechargeable aluminum ion batteries (RABs) have attracted much attention because of their high charge density, low cost, and low flammability. However, the traditional cathodes used in RABs had limited intercalation ability of Al3+ ion, leading to a low capacity. We report for the first time a rechargeable aluminum/iodine (Al/I2) battery. The unique conversion reaction mechanism of the Al/I2 battery chemistry avoids the cathode material disintegration during repeated charge–discharge processes, and this system successfully suppresses the shuttle of dissolved polyiodide in ionic liquid because of the hydrogen-bonding interaction, resulting in a robust rechargeable RAB system. The rechargeable Al/I2 battery based on the I3–/I– redox chemistry is demonstrated to be highly reversible in Al3+ ion storage, providing a high capacity of >200 mAh g–1 at 0.2C and high stability for even over 150 cycles at 1C. This work provides a new insight into designing a RAB system based on redox chemistry.
科研通智能强力驱动
Strongly Powered by AbleSci AI