材料科学
石墨
碳化
无定形碳
聚乙烯醇
化学工程
透射电子显微镜
催化作用
无定形固体
碳纤维
扫描电子显微镜
溶解
成核
复合材料
纳米技术
有机化学
化学
复合数
工程类
作者
О. П. Криворучко,Nadezhda I. Maksimova,В. И. Зайковский,Aleksei Salanov
出处
期刊:Carbon
[Elsevier]
日期:2000-01-01
卷期号:38 (7): 1075-1082
被引量:107
标识
DOI:10.1016/s0008-6223(99)00225-0
摘要
The catalytic graphitization of amorphous carbon matrix was carried out at the temperature range of 600–800°C in nitrogen atmosphere. Amorphous carbon matrix with uniformly distributed Fe particles was obtained via catalytic carbonization of polyvinyl alcohol (PVA) at temperatures up to 600°C in nitrogen atmosphere. Using transmission electron microscopy (TEM), selected area diffraction (SAD), scanning electron microscopy (SEM), and X-ray diffractometry (XRD), graphite structures of three types were found in products of catalytic graphitization of amorphous carbon matrix: multiwalled graphite shells wrapping the catalyst particles, cockle-shelled graphite filaments (CSF), and multiwalled graphite nanotubes (MWNT). We suppose that the formation of CSF proceeds through the dissolution of amorphous carbon in the metal, transformation of the catalyst particles into a liquid state, and transfer of dissolved carbon via intermediates to growing filaments. Graphite nanotubes nucleate at the matrix surface and then grow in the porous space of the matrix.
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