化学
壳聚糖
复合数
热重分析
电化学
X射线光电子能谱
电极
分子
不对称碳
玻璃碳
自组装
化学工程
循环伏安法
有机化学
物理化学
复合材料
材料科学
工程类
光学活性
作者
Hebing Pei,Fang Chen,Xiaohui Niu,Qianqian Jia,Ruibin Guo,Nijuan Liu,Zunli Mo
标识
DOI:10.1016/j.jelechem.2021.115525
摘要
Chitosan-sodium alginate (CS-SA) chiral composite sensing material was prepared by electrostatic self-assembly method. Scanning electron microscope images show that the morphologies of chitosan (CS) and sodium alginate (SA) have changed after self-assembly, which resulted in a new porous network structure. The structure and composition of the chiral composite sensing material were also identified by infrared spectroscopy, thermogravimetric analysis, and X-ray photoelectron spectroscopy. The self-assembled CS-SA chiral composite sensing material was drip-coated on the glass carbon electrode to construct an electrochemical sensing interface. The tested square wave voltammetry curve in the l-tyrosine (l-Tyr) and d-tyrosine (d-Tyr) solution presented that CS-SA chiral composite sensing material can specifically bind to l-tyrosine, and the binding force is determined as hydrogen bonding by the method of molecular docking calculation. Although chitosan molecules have abundant chiral sites, glassy carbon electrodes modified with pure CS molecules cannot effectively recognize tyrosine isomers. After being combined with sodium alginate by electrostatic self-assembly, the efficiency of chiral recognition is significantly improved. This experiment opens up a new method for the combination of chitosan with other materials, and at the same time, expands its application on chiral recognition.
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