功率密度
阴极
电解质
材料科学
离子
聚合物
电化学
离子键合
电压
密度泛函理论
化学工程
储能
能量密度
功率(物理)
电极
化学
复合材料
电气工程
热力学
物理化学
工程物理
计算化学
有机化学
物理
工程类
作者
Shuaifei Xu,Hongyu Dai,Shaolong Zhu,Yanchao Wu,Mingxuan Sun,Yuan Chen,Kun Fan,Chenyang Zhang,Chengliang Wang,Wenping Hu
出处
期刊:eScience
[Elsevier]
日期:2021-11-01
卷期号:1 (1): 60-68
被引量:88
标识
DOI:10.1016/j.esci.2021.08.002
摘要
Organic electrode materials have exhibited good electrochemical performance in batteries, but their voltages and rate capabilities still require improvement to meet the increasing demand for batteries with high energy and power density. Herein, we design and synthesize a branched dihydrophenazine-based polymer (p-TPPZ) as a cathode material for dual-ion batteries (DIBs) through delicate molecular design. Compared with the linear dihydrophenazine-based polymer (p-DPPZ, with a theoretical capacity of 209 mAh g–1), p-TPPZ possessed a higher theoretical capacity of 233 mAh g–1 and lower highest occupied molecular orbital energy levels,which resulted in a high actual capacity (169.3 mAh g–1 at 0.5 C), an average discharge voltage of 3.65 V (vs. Li+/Li) and a high energy density (618.2 Wh kg–1, based on the cathode materials). The branched structure of p-TPPZ led to a larger specific surface area than that of p-DPPZ, which was beneficial for the electrolyte infiltration and fast ionic transport, contributing to the high power density. Due to the fast reaction kinetics, even at a power density of 23,725 W kg–1 (40 C), the energy density still reached 474.5 Wh kg–1. We also made a detailed investigation of the p-TPPZ cathode's charge storage mechanism. This work will stimulate the further molecular design to develop organic batteries with both high energy and power density.
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