材料科学
木质纤维素生物量
咪唑酯
催化作用
光催化
制氢
兴奋剂
结晶度
硫化物
沸石咪唑盐骨架
金属有机骨架
化学工程
无机化学
核化学
水解
有机化学
化学
吸附
冶金
复合材料
工程类
光电子学
作者
Haruki Nagakawa,Morio Nagata
标识
DOI:10.1002/admi.202101581
摘要
Abstract Cu,In‐doped ZnS (CIZS) is fabricated from a metal–organic framework (MOF) precursor, namely a Cu,In‐doped zeolitic imidazolate framework (ZIF‐8). The prepared CIZS shows high activity for hydrogen production in the photoreforming reaction of lignocellulosic biomass under simulated sunlight. The activity is 125‐fold greater than that of undoped ZnS produced by the same method. Compared to CIZS synthesized by the conventional solvothermal method for sulfide photocatalysts, the CIZS synthesized via a MOF is characterized by high crystallinity and an 8.9‐fold increase in hydrogen production activity. This catalyst also exhibits better performance than conventional photoreforming catalysts, while it is free from toxic substances, such as Cd, or expensive cocatalysts, like Pt. In addition, the prepared CIZS is stable in photocatalytic reactions and achieves an apparent quantum yield of ≈28% under 360‐nm light irradiation.
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