异质结
材料科学
可见光谱
光电子学
多孔性
灵敏度(控制系统)
吸附
纳米技术
化学
电子工程
复合材料
工程类
有机化学
作者
Yu Liu,Xinghua Li,Xiaowei Li,Changlu Shao,Chaohan Han,Jiayu Xin,Dongxiao Lu,Luyao Niu,Yujing Tang,Yichun Liu
标识
DOI:10.1016/j.snb.2022.131926
摘要
Light-driven gas sensors that featured with simple device structure, intrinsic safety and room-temperature sensing characteristic have received increasing attention in recent years. However, it is still a great challenge for light-driven gas sensors to achieve high sensitivity due to the low utility of photo-generated carriers caused by the undesired recombination of carriers in the sensitive layer. Herein, a visible-light driven gas sensor based on hierarchical porous (HPS) WO3/CuWO4 heterostructure with unique interconnected framework is developed. The gas sensor exhibits high sensitivity (Rg/Ra=82) to NO2 (1 ppm) under visible-light illumination at room-temperature, which is 8.2, 12.6 and 3.5 times higher than the sensors based on pure HPS WO3, HPS CuWO4 and WO3/CuWO4 nanoparticles. On one hand, this exceptional high sensitivity is mainly derived from the low recombination of photo-generated carriers mediated by interfacial electric field effect of heterojunction, and on the other hand, the excellent sensing performance is related to the enhanced gas adsorption that endowed by the light irradiation and the rich reactive sites of the unique HPS structure of WO3/CuWO4. This study is expected to provide an important reference for designing other high-sensitive room-temperature light-driven gas sensors.
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