生物无机化学
电子顺磁共振
化学
金属有机化学
过渡金属
光谱学
电子顺磁共振波谱
光化学
纳米技术
材料科学
核磁共振
立体化学
有机化学
催化作用
物理
量子力学
作者
Minyoung Ju,Jin Kim,Jeongcheol Shin
摘要
Abstract Paramagnetic molecules, such as main‐group radicals and transition metal complexes, play crucial roles in catalytic and enzymatic reactions in organometallic and bioinorganic chemistry. Electron paramagnetic resonance (EPR) spectroscopy emerges as a powerful tool for probing the intricate electronic and geometric structures of these molecules. The application of EPR spectroscopy spans a wide spectrum of chemical entities, from simple radicals to transition metal complexes, metalloproteins, and metal clusters, emphasizing its versatility across various fields of chemistry. This review introduces the EPR spectra of transition metal complexes, offering a comprehensive theoretical foundation along with illustrative examples from both bioinorganic and organometallic chemistry. These examples highlight the effectiveness of EPR spectroscopy in characterizing transition metal complexes, reinforcing our understanding of their structure and reactivity.
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