One-step ethylene purification from ternary mixtures by an ultramicroporous material with synergistic binding centers

Developing advanced porous materials with industrial potential to separate multicomponent gas mixtures that are structurally similar is a crucial but challenging task. Here, we report the efficient one-step separation of ethylene (C2H4) from acetylene (C2H2) and carbon dioxide (CO2) using an ultramicroporous metal-organic framework UTSA-16. The synergistic effect of the polarized carboxyl groups and coordinated water molecules in its pore channel enables the material to have high uptakes for C2H2 and CO2 due to electrostatic potential matching, as well as excellent separation selectivity against C2H4. Breakthrough experiments suggest that UTSA-16 can efficiently separate 99.9% pure C2H4 from ternary mixtures with a high productivity of 403 L kg-1. Moreover, the preparation cost of UTSA-16 is significantly lower than other related adsorbents by 40-2000 times, indicating its unique potential for industrial applications.