兴奋剂
材料科学
氧化锡
导电体
锡
透明导电膜
光电子学
电导率
氧化物
电阻率和电导率
纳米技术
复合材料
冶金
电气工程
化学
物理化学
工程类
作者
Jianhui Guo,Rongrong Zhang,Cuiping Li,Chunhong Gong,Jiwei Zhang,Jingwei Zhang
标识
DOI:10.1016/j.matchemphys.2024.129476
摘要
In light of the three primary challenges faced by transparent conductive coatings, namely poor conductivity, elevated the active substance content, and insufficient visible light transmittance, net-like conductive agents due to the unique morphology and structure have been developed to address these concerns simultaneously. A straightforward synthesis of antimony-doped tin oxide (ATO) nanonets was accomplished through a simple two-step coprecipitation and hydrothermal methods. Firstly, an antimony-doped stannic hydroxide hydrogel precursor was generated through coprecipitation. Secondly, by adjusting the pH value in the hydrothermal reaction, ATO nanocrystals network were obtained without the need for additional materials. The synthesized ATO, with a net-like morphology, comprises particles of approximately 3-5 nm in diameter. Throughout the reaction, ammonium hydroxide, used as a pH regulator, played a vital role as a reducing agent in forming ATO nanonets without the need for further post-treatment. Moreover, net-like ATO compounded with SiO2 transparent conductive coatings exhibited exceptional transparent conductive properties, with a visible-light transmittance of approximately 84.7% at the wavelength of 550 nm and a square resistance of 0.5 kΩ/sq upon spin-coating deposition on glass. This remarkable performance can be attributed to the generation of a continuous conductive network. In comparison to granular ATO, the network structure ATO nanocrystal showcases a significant improvement in resistivity, demonstrating its exemplary transparent conductivity. The approach for the preparation of ATO nanonets was simple and easy to scale up to provide an enormous potential and broad prospect for the application of net-like ATO in transparent conductive coating.
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