Iron-carbon composite as flow electrode active material for highly efficient electrosorption of uranium from radioactive wastewater

放射性废物 废水 电极 复合数 碳纤维 材料科学 废物管理 化学 冶金 核化学 复合材料 工程类 物理化学
作者
En-Guang Zhao,Hang Lv,Junhao Fan,Haipeng Zhang,Sikai Wu,Yaozu Yin,Jixiang Guo,Shuxing Mei
出处
期刊:Separation and Purification Technology [Elsevier BV]
卷期号:: 128405-128405
标识
DOI:10.1016/j.seppur.2024.128405
摘要

A kind of iron-carbon composite for efficient electrosorption of uranium from radioactive wastewater was prepared by simply carbonization of cellulose and ferric nitrate, and the uranium electrosorption performance and behavior of the iron-carbon composite as flow electrode active material were investigated for low-concentration (below 50 mg/L) uranium-containing wastewater. By regulating the experimental conditions such as cellulose particle sizes, the mass ratio of cellulose/Fe(NO3)3, liquid flow rate, pH, and electric field strength, it was found that under the optimized conditions, the uranium removal ratios were 66.8, 81.92, 95.2, and 97.75 % for initial concentrations of 0.1, 0.5, 5.0, and 50.0 mg/L, respectively. The uranium concentration could be reduced from 0.1 mg/L to 0.0332 mg/L (the emission standard is 0.05 mg/L in China, GB 8798–1996) within 180 min of treatment. In addition, the material maintained an average salt removal rate of 26.27 μg cm−2 min−1 after 36 cycles of electrosorption. It achieved a uranium removal ratio of 87 %, and the upper limit of the electrosorption capacity was still not reached. Combined with X-ray photoelectron spectroscopy (XPS) analysis, the results indicated that the uranyl ion (UO22+) was firstly adsorbed on the surface of the active material after entering the flow electrode. Then, parts of the UO22+(Ⅵ) were reduced to uranium dioxide [UO2(Ⅳ)] under the synergistic action of zero-valent iron (ZVI) and cathodic electro-reduction and were finally immobilized on the electrode surface. This study proposed an innovative application of iron-carbon composite as flow electrode active material in FCDI for the treatment of uranium-containing wastewater with low-concentration (below 50 mg/L).
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