化学
铟
镓
齿合度
卤化物
第2组金属有机化学
铊
配位复合体
药物化学
路易斯酸
立体化学
分子
有机化学
金属
催化作用
作者
H. C. Clark,Amelia Pickard
标识
DOI:10.1016/s0022-328x(00)88856-7
摘要
The synthesis and stereochemistry of several classes of organoindium derivatives are described. Four-coordination about indium, in a distorted tetrahedral stereochemistry, is most common, and occurs in a series of 1:1 complexes of Lewis bases with dimethylindium halides and in two organoindium anions, dimethylindium dichloride and tetramethylindate. These new organoindium derivatives are similar to analogous aluminium and gallium compounds. 1:1 Complexes of dimethylindium halides with bidentate ligands (1,10-phenanthroline, 2,2′-bipyridine) were synthesized and probably contain five-coordinate indium. Several methylindium dichloride derivatives were synthesized and the parent compound is compared to the gallium and thallium analogues.
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