Synthesis of Primary Amines from Secondary and Tertiary Amines: Ruthenium‐Catalyzed Amination Using Ammonia

Splitting of secondary and tertiary amines! The first selective catalytic synthesis of primary amines from secondary and tertiary amines with ammonia is reported. The products are obtained in yields up to 84 %. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.