电容
电解质
电池(电)
锂(药物)
电化学
离子
双层电容
点(几何)
锂离子电池
双层(生物学)
材料科学
图层(电子)
电极
电子工程
化学
纳米技术
物理
数学
热力学
工程类
功率(物理)
医学
有机化学
物理化学
内分泌学
几何学
介电谱
作者
Nathalie Legrand,B. Davat,B. Knosp,Melika Hinaje,P Desprez,François Lapicque
标识
DOI:10.1016/j.jpowsour.2013.11.044
摘要
A fundamental model of lithium-ion battery cell based on Newman's works is presented in this article, including migration and diffusion of species and charges in electrodes and electrolyte. The particularity of our work is that the double layer capacitance, which is commonly neglected, is integrated in the model. We especially emphasize how to include correctly, in a physical point of view, the double layer capacitance in the electrochemical lithium-ion cell model. It is first demonstrated that the widely used mathematical formulation of the model leads to a physical error when the double layer capacitance is included, and a new formulation free of this error is proposed. Then are given the conditions for which the physical error mentioned before may cause appreciable inaccuracy in the prediction. Simulations have been carried out to validate the present analysis, and the results obtained show that the difference in cell voltage can attain several tens of millivolts.
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