Sustainable remediation of pesticide pollutants using covalent organic framework – A review on material properties, synthesis methods and application

Covalent organic frameworks (COF) have emerged as a potential class of materials for a variety of applications in a wide number of sectors including power storage, environmental services, and biological applications due to their ordered and controllable porosity, large surface area, customizable structure, remarkable stability, and diverse electrical characteristics. COF have received a lot of attention in recent years in the field of environmental remediation, It also find its way to eliminate the emerging pollutant from the environment notably pesticide from polluted water. This review more concentrated on the application of COF in pesticide removal by modifying COF structure, COF synthesis and material properties. To increase the adsorption ability and selectivity of the material towards certain pesticides removal, the synthesis of COF involves organic linkers with various functional groups such as amine, carboxylic acid groups etc. The COF have a high degree of stability and endurance make them suitable for intermittent usage in water treatment applications. This review manifests the novel progress where modified COFs employed in a prominent manner to remove pesticides from polluted water. Some examples of COF application in the eradication of pesticides are triformyl phenylene framework functionalized with amine groups has capacity to remove up to 50 mg/l of Organophosphorus – chlorpyrifos. COF modified to improve their photocatalytic capacity to breakdown the pesticide under visible light irradiation. COF tetraphenyl ethylene linked with carboxylic acid group shows efficient photocatalytic degradation of 90% of organochlorine insecticide endosulfan when subjected to visible light. Atrazine and imidacloprid are reduced from 100 ppm to 1 ppm in aqueous solutions by COF based on high adsorption capacity. In addition, the strategies, technique, synthesis and functional group modification design of COF are discussed.