Green Solvent Ethanol‐Based Inks for Industrially Applicable Deposition of High‐Quality Perovskite Films for Optoelectronic Device Applications

Abstract Incontrovertibly there is an increasing demand for the development of benign inks suitable for fabrication of high‐performing perovskite‐based thin film functional layers. Nevertheless, most reported perovskite precursors rely on the use of highly toxic solvents such as acetonitrile, 2‐methoxyethanol, dimethylformamide, and many others. Hence, there is a strong imperative for the development of novel and greener inks, which will facilitate smoother commercialization of technologies based on functional perovskite films. Therefore, four perovskite precursors are studied, some of which consist of up to 90% ethanol. All inks are developed to fulfill the requirements of a high‐throughput deposition compatible with roll‐to‐roll techniques at room temperature, assisted by an air knife for instant solvent removal. Two of the inks are particularly suitable for the fabrication of high‐quality and densely packed multi‐crystalline (CH 3 NH 3 )PbI 3 layers, as confirmed by numerous nanoscale spectroscopic and material characterization techniques. Additionally, large‐area photoluminescence (PL) imaging is demonstrated to improve the quality of the deposited perovskite films, with a route to enhance deposition uniformity when upscaling for manufacture. The genuine potential of the developed greener perovskite inks is demonstrated with the fabrication of solar cells with power conversion efficiencies above 19.5%.