材料科学
钝化
光电子学
电介质
单晶硅
咬边
多晶硅
兴奋剂
双层
微晶
硅
制作
氮化硼
纳米技术
复合材料
图层(电子)
冶金
膜
生物
遗传学
替代医学
病理
医学
薄膜晶体管
作者
Caroline Lima Anderson,Harvey Guthrey,William Nemeth,Chun‐Sheng Jiang,Matthew Page,Paul Stradins,Sumit Agarwal
标识
DOI:10.1016/j.mssp.2023.107655
摘要
State-of-the-art monocrystalline Si (c-Si) solar cells require passivating contacts to achieve a high degree of charge-carrier separation and collection. In this work, we focus on boron-doped polycrystalline Si on locally etched silicon nitride/silicon oxide (PLENO) passivating contacts. In PLENO contacts, excellent surface passivation is provided by the ∼10 nm dielectric bilayer, while pinholes in the dielectric bilayer, that are filled with doped polycrystalline Si, provide charge-carrier selectivity and transport. During PLENO fabrication, etch undercut in the dielectric bilayer occurs. Using electrical characterization and microscopies, we show that undercut causes pinholes to be electrically resistive in PLENO. A processing sequence that eliminates the undercut in the final PLENO structure results in electrically conductive pinholes with low contact resistivity.
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