化学
离子液体
烷基
热重分析
差示扫描量热法
溴化物
粘度
物理化学
离子键合
大气温度范围
分析化学(期刊)
热力学
离子
有机化学
催化作用
物理
作者
Milan Vraneš,Sanja Rackov,Snežana Papović,Renato Tomaš,Branka Pilić
标识
DOI:10.1021/acs.jced.2c00377
摘要
A series of 1-alkyl-3-vinylimidazolium-based ionic liquids (ILs) and salts that carry unsaturation in the head group on cation, ([CnC═Cim][Br], n = 2, 4, 6, 8, 10, and 12), were synthesized and characterized in the current study. Differential scanning calorimetry and thermogravimetric analysis were used to determine the thermal behavior and evaluate the phase changes of all the obtained ionic compounds. Further investigation was focused on ILs ([CnC═Cim][Br], n = 4, 6, and 8) and their dependence of temperature for density, electrical conductivity, and viscosity. The data were collected within the temperature range T = 293.15–343.15 K and at atmospheric pressure (p = 0.1 MPa). The transport properties for three ILs were analyzed using the Vogel–Fulcher–Tammann equation. The correlation between viscosity and molar conductivity has been examined using the Walden rule and ionicity, which indicates that the investigated ILs are found in the largest percentage in the form of ion pairs. The obtained experimental data were compared with the available values from the literature for their corresponding saturated counterparts elucidating the impact of the double bond.
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