Monolayer Interfacial Assembly toward Two‐Dimensional Mesoporous Heterostructure for Boosting Wave Absorption

Abstract Microwave absorption materials play a key role in various fields, including military stealth, human safety protection, and so on. Construction of 2D mesoporous heterostructures is an attractive approach to enhance wave‐absorbing ability, while it is still a great challenge. Herein, 2D mesoporous carbon‐MXene‐carbon heterostructures (MCMCH) with channels parallel to surface are successfully prepared via a monolayer interfacial assembly strategy. Through the precise adjustment and polymerization, cylindrical micelles orderly monolayered assemble on both surfaces of 2D MXene nanosheets, resulting in 2D switch‐like polydopamine‐MXene‐polydopamine nanosheets, and 2D MCMCH are finally generated by further calcination. Due to the excellent dielectric polarization relaxation and conductive loss, MCMCH achieves the strongest reflection loss of −54.2 dB at a thickness of only 1.5 mm. The presence of mesochannels not only introduces air with a low permittivity for optimal impedance matching, but also further extends the attenuation path of the incident electromagnetic wave. The maximum radar cross‐section reduction of 26.9 dB m 2 is achieved for the MCMCH compared to the perfect electric conductor. This work provides a reference for surface engineering based on 2D mesoporous heterostructures to enhance the microwave absorption performance.