缩水甘油醚
阻燃剂
环氧树脂
复合材料
呋喃
材料科学
极限抗拉强度
固化(化学)
双酚A
玻璃化转变
热固性聚合物
聚合物
复合数
热解
动态力学分析
有机化学
化学
作者
Hafezeh Nabipour,Xin Wang,Baljinder K. Kandola,Lei Song,Yongchun Kan,Jie Chen,Yuan Hu
标识
DOI:10.1016/j.polymdegradstab.2022.110206
摘要
The recycling of carbon fiber reinforced polymer composites (CFRPCs) is difficult because the thermosetting matrix is insoluble and does not melt. To overcome this problem, a furan-derived epoxy resin (HMF-GAN-EP) was synthesized from 5-hydroxymethylfurfural and cured with a furan-based curing agent (DIFFA). The cured HMF-GAN-EP/DIFFA system showed excellent flame retardancy (UL-94 V-0 and LOI of 40%). The glass transition temperature, tensile strength, and tensile modulus of the cured HMF-GAN-EP/DIFFA system were approximately 234 °C, 67 MPa and 2273 MPa, respectively, all of which were higher than those of the diglycidyl ether of bisphenol A (DGEBA)-type epoxy thermosets cured by 4,4′-diaminodiphenylmethane (DDM) (151 °C, 56 MPa and 1744 MPa). The cured HMF-GAN-EP/DIFFA system could dissolve in a mixed solution of THF:HCl (8:2, v/v), making it possible for the recycling of carbon fibers from CFRPCs.
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