纳米技术
生物医学
材料科学
化学
生化工程
组合化学
工程类
生物信息学
生物
作者
Rongtian Sheng,Ruimeng Sun,Li-Xia Chen,Ruijuan Lv,Yuhan Li,Ting Du,Yang Zhang,Yanfei Qi
标识
DOI:10.1080/10408347.2022.2073432
摘要
Artificial enzymes based on inorganic solids with both enzyme-mimetic activities and the special material features has been a promising candidate to overcome many deleterious effects of native enzymes in analytical applications. Polyoxometalates (POMs) are an importance class of molecular metal-oxygen anionic clusters. Their outstanding physicochemical properties, versatility and potential applications in energy conversion, magnetism, catalysis, molecular electronics and biomedicine have long been studied. However, the analytical applications of them is limited. Recently, the intrinsic enzymatic activities of POMs have also been found and become an area of growing interest. In this review, along with other reports, we aimed to classify the enzymatic activity of POMs, summarize the construction of POMs-based enzymes, and survey their recent advances in analytical fields. Finally, the current challenges and trends of the polyoxometalates with enzymatic activity in future chemo-/bio-sensing applications are briefly discussed.
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