催化作用
化学
纳米复合材料
反应性(心理学)
氧气
无机化学
十二面体
八面体
铜
化学工程
结晶学
纳米技术
晶体结构
材料科学
有机化学
病理
工程类
替代医学
医学
作者
Zhenhua Zhang,Liping Fan,Weiqi Liao,Feiyue Zhao,Cen Tang,Jing Zhang,Ming Feng,Ji-Qing Lu
标识
DOI:10.1016/j.jcat.2021.12.015
摘要
Several CeO2-CuO/Cu2O nanocomposites with different CuO structures were used to identify the structure sensitivity of CuO in the CeO2-CuO/Cu2O catalyzed CO oxidation. The CO oxidation catalyzed by various CuO-CeO2 interfacial sites involves a typical Mars-van Krevelen mechanism, in which the CuO-CeO2 interfaces in the CeO2-CuO/c-Cu2O (cubes) nanocomposites are more intrinsically active, exhibiting ca. 15 kJ mol−1 lower activation energy than those in the CeO2-CuO/o-Cu2O (octahedra) and CeO2-CuO/d-Cu2O (rhombic dodecahedra) nanocomposites at CeO2 loadings no less than 0.75 wt%. The higher activity is relevant to lower coordinated oxygen ions on CuO/c-Cu2O surface and thus better CO reactivity for the CeO2-CuO/c-Cu2O nanocomposites, which therefore indicates that the active oxygen species on CuO-CeO2 interface should come from CuO rather than CeO2. Moreover, a highly active 13.2 %CeO2-CuO/c-Cu2O(s) catalyst for CO oxidation is realized on fine Cu2O cubes, which thus has high density of active sites.
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