Single-junction polymer solar cells with high efficiency and photovoltage

Organic solar cells with efficiency greater than 10% are fabricated by incorporating a semiconductor polymer with a deepened valence energy level. Polymer solar cells are an exciting class of next-generation photovoltaics, because they hold promise for the realization of mechanically flexible, lightweight, large-area devices that can be fabricated by room-temperature solution processing1,2. High power conversion efficiencies of ∼10% have already been reported in tandem polymer solar cells3. Here, we report that similar efficiencies are achievable in single-junction devices by reducing the tail state density below the conduction band of the electron acceptor in a high-performance photoactive layer made from a newly developed semiconducting polymer with a deepened valence energy level. Control over band tailing is realized through changes in the composition of the active layer and the structure order of the blend, both of which are known to be important factors in cell operation4,5,6. The approach yields cells with high power conversion efficiencies (∼9.94% certified) and enhanced photovoltage.