过冷
统计物理学
动力非均质性
动力学(音乐)
相关函数(量子场论)
功能(生物学)
各向异性
分子动力学
焓
相关性
航程(航空)
玻璃化转变
热力学
物理
材料科学
数学
光学
量子力学
生物
进化生物学
电介质
复合材料
核磁共振
声学
聚合物
几何学
作者
Elijah Flenner,H.G. Staley,Grzegorz Szamel
标识
DOI:10.1103/physrevlett.112.097801
摘要
A few years ago it was shown that some systems that have very similar local structure, as quantified by the pair correlation function, exhibit vastly different slowing down upon supercooling. Recently, a more subtle structural quantity, the so-called ``point-to-set'' length, was found to reliably correlate with the average dynamics. Here we use computer simulations to examine the behavior of fluctuations around the average dynamics, i.e., dynamic heterogeneity. We study five model glass-forming liquids: three model liquids used in previous works and two additional model liquids with finite range interactions. Some of these systems have very similar local structure but vastly different dynamics. We show that for all these systems the spatial extent and the anisotropy of dynamic heterogeneity have the same correlation with the average dynamics. This result complements a recent experimental finding of a universal correlation between the number of correlated particles and the apparent activation enthalpy.
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