阳极
电解质
电池(电)
电化学
锂(药物)
材料科学
电极
锂离子电池
石墨
钛酸锂
离子
化学
化学工程
分析化学(期刊)
复合材料
功率(物理)
内分泌学
工程类
物理化学
有机化学
物理
医学
量子力学
色谱法
作者
Fu‐Ming Wang,Hsin‐Yi Wang,Menghan Yu,Yi-Ju Hsiao,Ying Tsai
标识
DOI:10.1016/j.jpowsour.2011.08.045
摘要
Solid electrolyte interface (SEI) formation is a key that utilizes to protect the structure of graphite anode and enhances the redox stability of lithium-ion batteries before entering the market. The effect of SEI formation applies a differential pulse (DP) and constant current (CC) charging on charge–discharge performance and cycling behavior into brand new commercial lithium ion batteries is investigated. The morphologies and electrochemical properties on the anode surface are also inspected by employing SEM and EDS. The electrochemical impedance spectra of the anode electrode in both charging protocols shows that the interfacial resistance on graphite anodes whose SEI layer formed by DP charging is smaller than that of CC charging. Moreover, the cycle life result shows that the DP charging SEI formation is more helpful in increasing the long-term stability and maintaining the capacity of batteries even under high power rate charge–discharge cycling. The DP charging method can provide a SEI layer with ameliorated properties to improve the performance of lithium ion batteries.
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