Ball milling synthesis of covalent organic framework as a highly active photocatalyst for degradation of organic contaminants

光降解 光催化 催化作用 三聚氰胺 研磨 球磨机 溶剂 苯酚 染色 结晶度 化学工程 化学 纳米技术 材料科学 共价键 有机化学 复合材料 工程类
作者
Hongzhou Lv,Xiaoli Zhao,Hongyun Niu,Sijing He,Zhi Tang,Fengchang Wu,John P. Giesy
出处
期刊:Journal of Hazardous Materials [Elsevier]
卷期号:369: 494-502 被引量:131
标识
DOI:10.1016/j.jhazmat.2019.02.046
摘要

Facile, environmentally-friendly fabrication of high-yield and stable covalent organic framework (COF) materials has been a limitation to their large-scale production and application. In this work, ball milling was used to synthesize COF by mechanochemical reaction between 1,3,5-triformylphloroglucinol (Tp) and melamine (MA) at ambient temperature. Different routes (liquid-free, solvent-assisted and catalyst-assisted) and proportions of liquids (solvents or catalyst) were investigated. Two morphologies were obtained when various amounts of liquid were added during grinding. The two forms were interwoven thread-shaped and exfoliative thin ribbon-like structures. Further, visible-light photocatalytic (λ > 400 nm) performance and mechanism of the two structures of COFs were investigated. The exfoliative ribbon-like structures exhibited greater rates of photodegradation of phenol and retained 87.6% of initial photodegradation after being used four times. Addition of liquid catalyst not only improved crystallinity of the COF materials, but also enhanced rates of photocatalytic reactions. Photocatalytic activity of the exfoliative structure of TpMA synthesized by ball milling was comparable with that of the photocatalyst prepared by use of the solvothermal method, while time to prepare the catalyst was shortened by 36-fold and the amount of solvent used was reduced by 8-fold at room temperature. Mechanochemical synthesis is a promising potential tool for large-scale production of COFs, which will make greater use of COFs for degradation of pollutants.
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