MXene materials, which consist of nitrides, carbides, or carbonitrides of transition metals, possess a distinctive multilayered structure resulting from the specific etching of the "A" layer from MAX phase precursors. This unique structure allows for tunable properties through intercalation and surface modification. Beyond their structural novelty, MXenes exhibit exceptional thermal conductivity, mechanical resilience, and versatile surface functionalization capabilities, rendering them highly versatile for a wide range of applications. They are particularly renowned for their multifaceted utility and are emerging as outstanding candidates in applications requiring robust thermal conductivity. MXenes, when integrated into textile, fiber, and film forms, have gained increasing relevance in fields where efficient heat management is essential. This work provides a comprehensive exploration of MXene materials, delving into their inherent structure and thermal properties. This Perspective places particular emphasis on their crucial role in efficient heat dissipation, which is vital for the development of wearable heaters and related technologies. Engineered compounds such as MXenes have become indispensable for personal and industrial heating applications, and the advancement of wearable electronic devices necessitates heaters with specific properties, including transparency, mechanical reliability, and adaptability. Recent advancements in emergent thermally conductive MXene compounds are discussed in this study, shedding light on their potential contributions across various domains, including wearable heaters and biosensors for healthcare and environmental monitoring. Furthermore, the versatile nature of MXene materials extends to their application in interfacial solar steam generation, representing a breakthrough approach for solar water desalination. This multifaceted utility underscores the vast potential of MXenes in addressing various pressing challenges.