聚乙烯醇
材料科学
聚酰胺
钍
离子
酒
化学工程
高分子化学
有机化学
复合材料
铀
冶金
工程类
化学
作者
Mohamed A. Hendy,Tahani I. Kashar,Eman M. Allam,Mohamed A. Gado,Naema S. Yahia,Mohamed F. Cheira
标识
DOI:10.1016/j.mtcomm.2024.109633
摘要
Chemical disposal via adsorption of radioactive waste is the safest technique for the ecosystem because thorium is a radioactive and harmful environmental material that needs to be disposed of safely. Herein, a unique, highly efficient, and inexpensive sorbent is employed to withdraw thorium ions. A functionalized sulfosuccinic acid on polyvinyl alcohol/polyamide (SSA/PVA/PA) was synthesized via a wet processing technique. The synthesized SSA/PVA/PA was distinguished utilizing XRD, SEM-EDX, FTIR, BET, TGA, and XPS assessment. The data denoted that the SSA/PVA/PA was well made. The thorium removal onto SSA/PVA/PA poly-adsorbent was checked, which authorized that the SSA/PVA/PA exposed excellent adsorption assets for thorium ions in waste solution. The extreme thorium uptake was 142.11 mg/g at pH 3.5, 75 min contacting time, 50 mg SSA/PVA/PA dose, and 100 mg/L primary Th(IV) concentration. The Langmuir and the pseudo-second-order (PSO) modelings may be excellent fits for the sorption experiments. Adsorption of Th(IV) to the SSA/PVA/PA was determined to be exothermic and spontaneous by the thermodynamic investigations. The optimal desorption specifications of thorium ions from Th/SSA/PVA/PA were also acquired. Also, the SSA/PVA/PA was definitely regenerated by 1:50 S:L ratio, 1.25 M Na2CO3, and 0.25 M of sodium malonate for 60 min contacting. The adsorption-desorption testing was supervised to explore the applied pertinence and repetitive utilization of SSA/PVA/PA at six cycles. Based on the outcomes, the SSA/PVA/PA might be employed as a prospective sorbent for eliminating thorium from water.
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