自愈水凝胶
材料科学
纳米颗粒
吸附
乙烯醇
原位聚合
多孔性
化学工程
聚合物
聚合
金属有机骨架
纳米技术
灵活性(工程)
复合材料
高分子化学
化学
有机化学
工程类
统计
数学
作者
Yiliang Wang,Hui Peng,Haomin Wang,Mingchao Zhang,Wei Zhao,Yingying Zhang
标识
DOI:10.1016/j.cej.2022.138216
摘要
Metal–organic framework (MOF) composites shaped by hydrogels have the advantages of abundant pores, diverse functional groups, and excellent flexibility, showing tremendous potential in many fields. However, many used hydrogels are prepared by chemical cross-linking or polymerization reactions, and the synthesized MOF microparticles are aggregated and easily fall out. Here, we report the in-situ synthesis of MOF nanoparticles (<100 nm) in the poly(vinyl alcohol)@alginate double-network hydrogels, which are further used for fabricating stretchable MOF hydrogel tubes. The high-modulus nanoparticles can serve as strong crosslinks and enhance the entanglements of polymer chains, improving the mechanical properties of the composites significantly. Furthermore, the porous nanoparticles endow the hydrogels with unique recovery behavior from compression and good adsorption properties. This study opens up new horizons in the controllable preparation of soft MOF hydrogel composites for many promising applications.
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