Ionic-liquid materials for the electrochemical challenges of the future

离子液体 电化学 离子键合 材料科学 纳米技术 化学工程 离子 化学 工程类 有机化学 电极 物理化学 催化作用
作者
Michel Armand,Frank Endres,Douglas R. MacFarlane,Hiroyuki Ohno,Bruno Scrosati
出处
期刊:Co-Published with Macmillan Publishers Ltd, UK eBooks [Co-Published with Macmillan Publishers Ltd, UK]
卷期号:: 129-137 被引量:118
标识
DOI:10.1142/9789814317665_0020
摘要

Materials for Sustainable Energy, pp. 129-137 (2010) No AccessIonic-liquid materials for the electrochemical challenges of the futureMichel Armand, Frank Endres, Douglas R. MacFarlane, Hiroyuki Ohno, and Bruno ScrosatiMichel ArmandLRCS CNRS 6007, Université de Picardie Jules Verne, F-80039 Amiens, France, Frank EndresInstitute of Particle Technology, Clausthal University of Technology, D-38678 Clausthal-Zellerfeld, Germany, Douglas R. MacFarlaneSchool of Chemistry and ARC Centre of Excellence for Electromaterials Science, Monash University, Clayton, Victoria 3800, Australia, Hiroyuki OhnoDepartment of Biotechnology, Tokyo University of Agriculture and Technology, Tokyo 184-8588, Japan, and Bruno ScrosatiDepartment of Chemistry, University Sapienza, 00185 Rome, Italyhttps://doi.org/10.1142/9789814317665_0020Cited by:24 PreviousNext AboutSectionsPDF/EPUB ToolsAdd to favoritesDownload CitationsTrack CitationsRecommend to Library ShareShare onFacebookTwitterLinked InRedditEmail Abstract: Ionic liquids are room-temperature molten salts, composed mostly of organic ions that may undergo almost unlimited structural variations. This review covers the newest aspects of ionic liquids in applications where their ion conductivity is exploited; as electrochemical solvents for metal/semiconductor electrodeposition, and as batteries and fuel cells where conventional media, organic solvents (in batteries) or water (in polymer-electrolyte-membrane fuel cells), fail. Biology and biomimetic processes in ionic liquids are also discussed. In these decidedly different materials, some enzymes show activity that is not exhibited in more traditional systems, creating huge potential for bioinspired catalysis and biofuel cells. Our goal in this review is to survey the recent key developments and issues within ionic-liquid research in these areas. As well as informing materials scientists, we hope to generate interest in the wider community and encourage others to make use of ionic liquids in tackling scientific challenges. 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Jénnifer Gómez, Manuel Vázquez Sulleiro, Daniele Mantione and Nuria Alegret27 February 2021 | Polymers, Vol. 13, No. 5Synthesis and mesomorphism of related series of triphilic ionic liquid crystals based on 1,2,4-triazolium cationsAlessio Riccobono, Giuseppe Lazzara, Sarah E. Rogers, Ivana Pibiri and Andrea Pace et al.1 Jan 2021 | Journal of Molecular Liquids, Vol. 321On the molecular mechanisms of α and β relaxations in ionic liquidsElisa Steinrücken, Manuel Becher and Michael Vogel14 Sep 2020 | The Journal of Chemical Physics, Vol. 153, No. 10Atomic Force and Scanning Tunneling Microscopy of Ordered Ionic Liquid Wetting Layers from 110 K up to Room TemperatureManuel Meusel, Matthias Lexow, Afra Gezmis, Simon Schötz and Margareta Wagner et al.1 July 2020 | ACS Nano, Vol. 14, No. 7Optimization of the Carbon Content in Copper Phosphide–Carbon Composites for High Performance Sodium Secondary Batteries Using Ionic LiquidsShubham Kaushik, Kazuhiko Matsumoto, Yuta Sato and Rika Hagiwara10 June 2020 | ChemElectroChem, Vol. 7, No. 11Confining Liquids inside Carbon Nanotubes: Accelerated Molecular Dynamics with Spliced, Soft-Core Potentials and Simulated AnnealingAusten Bernardi, Eric R. 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