Preparation and characterization of three-dimensional hierarchical porous carbon from low-rank coal by hydrothermal carbonization for efficient iodine removal

Low-rank coal, such as Shengli lignite (SL) and Datong bitumite (DT), has abundant reserves and is low in cost. Due to its high moisture content, abundant oxygen-containing groups, high ash content and low calorific value, low-rank coal is mainly used in a low-cost method of direct combustion. For better value-added utilization of SL and DT, a novel strategy has been developed for the preparation of oxygen-rich hierarchical porous carbons (HPCs) by hydrothermal carbonization (HTC), followed by steam activation. In this paper, firstly, the physical and chemical properties of SL and DT were improved by HTC pretreatment, bringing them closer to high rank coal. Then, the effects of HTC pretreatment and activation temperature on the properties of the HPCs were investigated in detail. The results show that the HPCs have mainly microporous structures (the microporosity of 200-SLHPC-900 is 79.58%) based on the N