荧光粉
化学
光致发光
离子
分析化学(期刊)
兴奋剂
吸收(声学)
发光
热稳定性
猝灭(荧光)
辐照
荧光
光电子学
材料科学
光学
物理
复合材料
有机化学
核物理学
色谱法
作者
Yanyan Li,Yurong Shi,Ge Zhu,Quansheng Wu,Hao Li,Xicheng Wang,Qian Wang,Yuhua Wang
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2014-06-26
卷期号:53 (14): 7668-7675
被引量:69
摘要
A series of single-component Ce3+, Li+, Mn2+ ions codoped color-tunable CaSr2Al2O6 phosphors were synthesized by a high-temperature solid-state reaction, and the photoluminescence properties as well as the energy transfer mechanism from Ce3+ to Mn2+ ions have been investigated in detail. The Ce3+ activated phosphors have strong absorption in the range of 250–420 nm and can give a blue emission centered at about 460 nm. When Mn2+ ions are codoped, the emission of CaSr2Al2O6:Ce3+, Li+, Mn2+ phosphors can be tuned from blue to red through adjusting the doping concentration of the Mn2+ ions, under the irradiation of 358 nm. When the concentration of Mn2+ is increased to 0.02, a warm-white light can be obtained with good CIE coordinates of (0.388, 0.323) and a low CCT of 3284 K. The energy transfer mechanism from the Ce3+ to Mn2+ ions is demonstrated to be a quadrupole–quadrupole interaction based on the analysis of the decay curves of the phosphors. The thermal quenching stability was also investigated. The results indicate that CaSr2Al2O6:Ce3+, Li+, Mn2+ samples might have potential applications in w-LEDs.
科研通智能强力驱动
Strongly Powered by AbleSci AI