析氧
电催化剂
双功能
杂原子
材料科学
氮化物
电解
电解质
化学工程
兴奋剂
分解水
电流密度
无机化学
纳米技术
电极
催化作用
化学
电化学
物理化学
光电子学
有机化学
工程类
物理
光催化
量子力学
图层(电子)
戒指(化学)
作者
Huafeng Fan,Wei Chen,Guangliang Chen,Jun Huang,Changsheng Song,Yun Du,Chaorong Li,Kostya Ostrikov
标识
DOI:10.1016/j.apcatb.2019.118440
摘要
Bi-functional electrocatalysts capable to simultaneously sustain hydrogen and oxygen evolution reactions (HER, OER) under industry-relevant conditions of hydrogen production by water electrolysis are highly desired. Here, we implement a new concept of plasma-enabled simultaneous N-P heteroatom doping to achieve the highly-competitive activity and stability of trimetallic Ni-V-Fe bi-functional electrocatalysts on a NiFe foam (N-NiVFeP/NFF), evidenced by the lower overpotentials for HER (79 mV) and OER (229 mV) to deliver a current density of 10 mA cm−2 (j10) in the 1.0 M KOH electrolyte. Meanwhile, the N-NiVFeP/NFF exhibits ultra-stable performances with a current density from 10 to 100 mA cm-2 for over 100 h. Specifically, the HER and OER performances are near to those of noble-metal based electrocatalysts in the high current density region (> j200), attributing to the rich active sites exposed on the formed heterointerfaces among Ni-V-Fe phospho-nitrides, the changed electronic structure, and increased conductivity with nitrogen doping.
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